The cage effect can be quantitatively described as the cage recombination efficiency Fc where:
$${\displaystyle F_{c}=k_{c}/(k_{c}+k_{d})}$$
Here Fc is defined as the … 詳細

In free radical polymerization, the rate of initiation is dependent on how effective the initiator is. Low initiator efficiency, ƒ, is largely attributed to the cage effect. The rate of initiation is described as:
$${\displaystyle R_{i}=2fk_{d}[I]}$$
where Ri is the rate of … 詳細

• Solvent effects
• Carrier generation and recombination
• Rate-determining step 詳細